STEREOELECTRONIC EFFECTS KIRBY PDF

This primer describes how stereoelectronic effects control this behavior. It is the only concise text on this topic at the undergraduate level. This is an important subject area and the comprehensive yet concise coverage in this book shows students how to build up a powerful but simple way of thinking about chemistry. From the Back Cover: This series of short texts provides accessible accounts of a range of essential topics in chemistry. Written with the needs of the student in mind, the Oxford Chemistry Primers offer just the right level of detail for undergraduate study, and will be invaluable as a source of material commonly presented in lecture courses yet not adequately covered in existing texts.

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This primer describes how stereoelectronic effects control this behavior. It is the only concise text on this topic at the undergraduate level. This is an important subject area and the comprehensive yet concise coverage in this book shows students how to build up a powerful but simple way of thinking about chemistry. From the Back Cover: This series of short texts provides accessible accounts of a range of essential topics in chemistry.

Written with the needs of the student in mind, the Oxford Chemistry Primers offer just the right level of detail for undergraduate study, and will be invaluable as a source of material commonly presented in lecture courses yet not adequately covered in existing texts.

All the basic principles and facts in a particular area are presented in a clear and straightforward style, to produce concise yet comprehensive accounts of topics covered in both core and specialist courses.

Although there are a vast numbers of reactions known, these may be grouped into a small number of mechanistic classes, then into a still smaller set of classes of stereoelectronic interaction. Stereoelectronic effects is deliberately non-mathematical in its approach, with reactions illustrated by real examples. It should provide the student with an understanding of fundamental relationships and a powerful but simple approach to thinking about Chemistry.

About the Author: Antony J. Kirby is at University of Cambridge.

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Stereoelectronic Effects (Oxford Chemistry Primers)

For donating orbitals, the nonbonding orbitals, or the lone pairs, are generally more effective than bonding orbitals due to the high energy levels. Also, different from acceptors, donor orbitals require less polarized bonds. The radius of sulfur is much larger than the radius of carbon and oxygen. The shorter the difference is, the better the interaction and the stronger the stereoelectronic effect. Generally, the substitution of hydrogen by fluorine could be regarded as a way to tune both the hydrophobicity and the metabolic stability of a drug candidate. Moreover, it can have a profound influence on conformations, often due to stereoelectronic effects, in addition to normal steric effects resulting from the larger size of the fluorine atom.

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Stereoelectronic Effects

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